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The state denoted by f is a saturated liquid state. The saturated vapor line separates the vapor region and the two-phase liquid-vapor region. The state denoted by g is a saturated vapor state. The saturated liquid line and the saturated vapor line meet at the critical point. At the critical point, the pressure is the critical pressure pc, and the temperature is the critical temperature Tc . Three phases can coexist in equilibrium along the line labeled triple line. The triple line projects onto a point on the phase diagram.
The Kelvin-Planck statement of the second law can be given as follows: It is impossible for any system to operate in a thermodynamic cycle and deliver a net amount of energy by work to its surroundings while receiving energy by heat transfer from a single thermal reservoir. In other words, a perpetualmotion machine of the second kind is impossible. Expressed analytically, the Kelvin-Planck statement is Wcycle ≤ 0 (single reservoir) where the words single reservoir emphasize that the system communicates thermally only with a single reservoir as it executes the cycle.
41) This equation is primarily empirical in nature, with no rigorous justification in terms of molecular arguments. 9. Modified forms of the equation have been proposed with the aim of achieving better accuracy. © 2000 by CRC Press LLC Although the two-constant Redlich-Kwong equation performs better than some equations of state having several adjustable constants, two-constant equations tend to be limited in accuracy as pressure (or density) increases. Increased accuracy normally requires a greater number of adjustable constants.